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Oxidation Reduction problems

 
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Hashimbuba3155



Joined: 21 Apr 2008
Posts: 2

PostPosted: Sun May 18, 2008 10:40 pm    Post subject: Oxidation Reduction problems Reply with quote

I have a quick question on these types of problems involving electrochemistry. When given the Ecell of two 1/2 reactions, how do you go about determining whether to flip the sign of one as opposed to the other. These problems are giving me fits...

Thanks in advance!
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PostPosted: Sat May 24, 2008 2:51 pm    Post subject: Reply with quote

Your objective with these problems is to end up with the highest positive Eo value: that's it, that's all.

For example, if there is a reduction potential table and the Eo values are 3 and 2. The equation with Eo = 3 will occur as written because it has the highest value and the other equation will be switched so that that half cell has Eo = -2.

Keep in mind: positive Eo values for a cell suggests that the reaction would proceed spontaneously as written.
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