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admin Site Admin
Joined: 08 Dec 2003 Posts: 2176
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Posted: Tue Jul 21, 2009 2:16 pm Post subject: Question 31 |
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sbains3528
Joined: 16 Aug 2010 Posts: 14
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Posted: Thu Aug 26, 2010 1:39 pm Post subject: |
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31) Phenols are soluble in a strongly basic sodium hydroxide solution, and insoluble in dilute sodium bicarbonate. Phenol has a pKa = 10.0. The introduction of an ortho bromine atom into the phenol would have the effect of
1. lowering the pKa and thus decreasing the acidity of the phenol.
2. lowering the pKa and thus increasing the acidity of the phenol.
3. increasing the pKa and thus decreasing the acidity of the phenol.
4. increasing the pKa and thus increasing the acidity of the phenol.
Can someone explain this to me? The answer was B. |
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j5devries4378
Joined: 07 Aug 2010 Posts: 5
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Posted: Thu Aug 26, 2010 9:24 pm Post subject: |
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| Yeah I am confused too... I thought adding an electron donating group would activate the ring, and increase acidity. This increased acidity decrease the pKa and increase the Ka. |
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