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formal charge

 
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alexielzhang
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PostPosted: Sat Feb 06, 2010 12:16 pm    Post subject: formal charge Reply with quote

how do you calculate formal charge of carbon in a carbonate ion? I thought it would be positive one. Reasoning: carbonate ion has total of negative charge of 2. Carbon is capable of four bonds. Three binds Oxygen. Thus, each oxygen has formal charge of (-1). Addition of all charges give total of (-2). And carbon has (+1) formal charge.
But apparently the answer is zero. How is that?
Thanks
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emilie.maz5603



Joined: 01 Feb 2010
Posts: 15

PostPosted: Fri Apr 09, 2010 10:04 am    Post subject: Reply with quote

The Carbonate ion = CO₃²⁻

To calculate the Formal charge of each atom in a formula, you need the following equation:

Formal charge (FC) of each atom = no. of valence electrons – (no. of unshared valence e- + ½ shared valence e-)

So for Carbon, FC = 4 valence e- – [0 unshared e- + ½(8 shared e-) = 4 – [0+4] = 4 – 4 = 0
So, Carbon = 0 that is correct!


Last edited by emilie.maz5603 on Sat Apr 10, 2010 5:03 am; edited 2 times in total
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