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admin Site Admin
Joined: 08 Dec 2003 Posts: 2168
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Posted: Sun May 06, 2007 8:48 pm Post subject: proton nmr, organic acid |
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Yes, you are correct that a carboxylic acid has an acidic hydrogen. However, from the question, all that we can conclude is that compound X lost a proton and is therefore an acid. Do we know what kind of acid it is? Carboxylic acids are the most common organic acid but there are many other options: sulfonic acids are actually more acidic than carboxylic acids, then there are weaker acids with functional groups like -OH, -SH, -enol, etc.
In other words, answer choice B is the best answer because it is the one thing that we can be sure of. |
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dnpgr16513
Joined: 14 Jun 2010 Posts: 73
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Posted: Tue Jun 29, 2010 7:20 pm Post subject: |
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I don't understand why this answer isn't D. Aldehydes only have 1 type of proton, so in a reaction, the observance of the disappearance of a hydrogen wouldn't signify that it was an aldehyde?
Thanks. |
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calena7178147
Joined: 26 Jan 2010 Posts: 43
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Posted: Tue Jul 20, 2010 1:49 pm Post subject: |
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| Answer B is correct. Aldehydes do not all have only one type of protons. In particular when the carbon chain is long you have also protons attached to the carbon. Aldehydes have the following structure of RCOH. In addition, an acidic proton is lost with D2O replacement as stated and so B makes the most sense. |
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